\(a,n_{H_2}=\dfrac{2,576}{22,4}=0,115\left(mol\right)\\ Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}95a+133,5b=10,475\\a+1,5b=0,115\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,04\\b=0,05\end{matrix}\right.\\ \%m_{Mg}=\dfrac{0,04.24}{0,04.24+0,05.27}.100\approx41,558\%\Rightarrow\%m_{Al}\approx58,442\%\\ b,n_{HCl}=2.n_{H_2}=2.0,115=0,23\left(mol\right)\\ \Rightarrow x=C\%_{ddHCl}=\dfrac{0,23.36,5}{100}.100=8,395\%\)

a) Gọi số mol Zn, Fe là a, b (mol)

=> 65a + 56b = 8,56 (1)

\(n_{H_2}=\dfrac{3,136}{22,4}=0,14\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

           a--->2a-------->a----->a

            Fe + 2HCl --> FeCl₂ + H₂

           b----->2b------->b------>b

=> a + b = 0,14 (2)

(1)(2) => a = 0,08; b = 0,06 

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,08.65}{8,56}.100\%=60,748\%\\\%m_{Fe}=\dfrac{0,06.56}{8,56}.100\%=39,252\%\end{matrix}\right.\)

b) 

n_KOH = 0,2.0,1 = 0,02 (mol)

PTHH: KOH + HCl --> KCl + H₂O

           0,02-->0,02

=> n_HCl = 0,02 + 2a + 2b = 0,3 (mol)

=> \(C_{M\left(HCl\right)}=xM=\dfrac{0,3}{0,15}=2M\)

c) m = 0,08.136 + 0,06.127 = 18,5(g)

a) Đặt \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow27a+56b=11\)  (1)

Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

Bảo toàn electron: \(3a+2b=0,4\cdot2=0,8\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{11}\cdot100\%\approx49,09\%\\\%m_{Fe}=50,91\%\end{matrix}\right.\)

b) Bảo toàn nguyên tố: \(\left\{{}\begin{matrix}n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\\n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{muối}=m_{AlCl_3}+m_{FeCl_2}=0,2\cdot133,5+0,1\cdot127=39,4\left(g\right)\)

c) Bảo toàn electron: \(3\cdot0,2+3\cdot0,1=2n_{SO_2}\)

\(\Rightarrow n_{SO_2}=0,45\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,45\cdot22,4=10,08\left(l\right)\)

a) Gọi nAl = x, nFe = y

Có 27x + 56y = 11 (1)

Bảo toàn e

3x + 2y = 2.0,4 (2)

Từ 1 và 2 => x = 0,2, y = 0,1

\(\%mAl=\dfrac{0,2.27}{11}.100\%=49,09\%\)

\(\%mFe=100-49,09=50,91\%\)

b) BTKL: 

m muối = mkim loại + mHCl - mH2

= 11 + 0,4.2.36,5 - 0,4.2 = 39,4g

c) 

Bảo toàn e

Al => Al⁺³ + 3e                                  S⁺⁶ + 2e => S⁺⁴

0,2               0,6                                             2x          x

Fe => Fe⁺³ + 3e

0,1                  0,3

=> 2x = 0,6 + 0,3 => x = 0,45 mol

=> VSO₂ = 0,45.22,4 = 10,08 lít

\(n_{H_2}=\dfrac{17,353}{24,79}=0,7\left(mol\right)\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=27,8\\1,5a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\\ a,\%m_{Al}=\dfrac{0,2.27}{27,8}.100\%=19,424\%\\\Rightarrow\%m_{Fe}=80,576\%\\ b,n_{HCl}=3a+2b=1,4\left(mol\right)\\ m_{ddHCl}=\dfrac{1,4.36,5.100}{20}=255,5\left(g\right) \Rightarrow4\approx\approx\approx\Rightarrow FeHCm=\)

Gọi số mol Al, Fe là a, b

\(m_{Cu}=m_B=6,4\left(g\right)\)

=> \(m_{Al}+m_{Fe}=17,4-6,4=11\left(g\right)\)

=> 27a + 56b = 11

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂ 

            b----------------------->b

            2Al + 6HCl --> 2AlCl₃ + 3H₂

             a------------------------>1,5a

=> 1,5a + b = 0,4

=> a = 0,2; b = 0,1

=> \(\left\{{}\begin{matrix}m_{Fe}=0,1.56=5,6\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)

Gọi: \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\) ⇒ 27x + 56y = 5,5 (1)

PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{3}{2}x+y=\dfrac{4,48}{22,4}=0,2\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{5,5}.100\%\approx49,09\%\\\%m_{Fe}\approx50,91\%\end{matrix}\right.\)

Gọi nFe = a (mol); nAl = b (mol)

=> 56a + 27b = 11 (1)

nH2 = 8,96/22,4 = 0,4 (mol)

PTHH: 

Fe + 2HCl -> FeCl2 + H2

a ---> 2a ---> a ---> a

2Al + 6HCl -> 2AlCl3 + 3H2

b ---> 1,5b ---> b ---> b

=> a + 1,5b = 0,4 (2)

Từ (1)(2) => a = 0,1 (mol); b = 0,15 (mol)

mFe = 0,1 . 56 = 5,6 (g)

mAl = 0,2 . 27 = 5,4 (g)

THAM KHẢO :
 

Fe + 2HCl -> FeCl₂ + H₂ (1)

a) 2Al + 6HCl -> 2AlCl₃ + 3H₂ (2)

Gọi khối lượng Fe là x(g) (0<x<11) => n_Fe = x/56 (mol)

Thì m_Al là 11-x(g) => n_Al = (11-x)/27 (mol)

n_H2 = 8,96/22,4 = 0,4 (mol)

Theo PT (1) ta có: n_H2 = n_Fe = x/56 (mol)

Theo PT (2) ta có: n_H2 = 3/2 n_Al = 3/2 . (11-x)/27 = (11-x)/18 (mol)

Theo đề bài, n_H2 thu được là 0,4(mol) nên ta có:

x/56 + (11-x)/18 = 0,4

<=> 18x +56(11-x) = 403,2

<=> x = 5,6 (g)

Do đó: m_Fe = 5,6(g) => n_Fe = 5,6/56 = 0,1 (mol)

m_Al = 11-5,6 = 5,4(g) => n_Al = 5,4/27 = 0,2 (mol)

\(a,n_{H_2}=\dfrac{6,72}{22,4}=0,3(mol)\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow n_{Al}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ b,m_{hh}=5,4+12,8=18,2(g)\\ c,n_{HCl}=0,6(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,3}=2M\)

a) \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

_____0,2<----0,6<---------------0,3

=> m_Al = 0,2.27 = 5,4(g)

b) m_hh = 5,4 + 12,8 = 18,2(g)

c) \(C_{M\left(HCl\right)}=\dfrac{0,6}{0,3}=2M\)